Secondary colors are made by mixing two primary colors together: red and yellow to get orange, yellow and blue to get green, or red and blue to get purple. The secondary color you get depends on the proportions in which you mix the two primaries. If you mix three primary colors together, you get a tertiary color. Secondary colors are made by mixing two primary colors together. Red and yellow make orange; red and blue make purple yellow and blue make green.
Red and yellow always make some kind of orange, yellow and blue a green, and blue and red a purple. The actual color you get depends on which primary you're using (for example whether it's Prussian blue or ultramarine you're mixing with cadmium red) and the proportions in which you mix the two primaries. Paint a color chart where you record which two colors you mixed and the (approximate) proportions of each. This will provide you with a ready reference until you get to the stage when you instinctively know what you'll get.
Color Theory Lesson
Color Theory Lesson - Warm and Cool Colors
Color Theory Lesson -Tertiary Colors
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