Browns and grays contain all three primary colors. They're created by mixing either all three primary colors or a primary and secondary color (secondary colors of course being made from two primaries). By varying the proportions of the colors you're mixing, you create the different tertiary colors.
If you mix too many colors together, you'll get mud. If your gray or brown isn't coming out the way you want it to, rather start again than add more color in the hope it'll work.
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